If the store is down, this is both bad news and good news.
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It could be that the App Store is down and nobody can access it. The quickest way of finding out is to check Apple's System Status page, which lists problems with all of the company's online services; the App Store is first on the list.
Note that if the problem occurred very recently it may not have been noticed yet: the site's update frequency is in the order of minutes, not seconds.
It's an obvious one, but you need to be online to access the App Store.
Make sure you're connected to the internet - visit Google, for example.
While using your mobile network connection shouldn't stop you from accessing the App Store entirely, if your i Phone is set to only download apps over Wi Fi you won't be able to download apps over a 3G/4G connection.