If you create a sub-subfolder, it will not show up in Tunes.
Subfolders will show up as individual photo albums in i Tunes, You can then check or uncheck each folder in order to sync them or not.
4: Click on the Sharing tab and deselect everything (same goes for Store and Parental). and select Prevent i Pod's, i Phone's, and i Pad's from syncing automatically, deselect [b]Warn when more than ? Deselect Allow i Tunes audio control from remote speakers and Reset sync history. Reset Warnings, and Cache and Music Location7: Delete Music, Videos, Apps, etc.
8: Open and disable any un-needed services: Apple Mobile Device - If you have no apple devices (i Phone, i Pod, Apple TV). You could try Reinstalling i Tunes, updating i Tunes using Apple Software Update. Sometimes when I sleep the PC and wake it again it is open.
You can also use subfolders to help organize and sync only certain photos you want on the i Phone/i Pod.